High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator.

Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated reactions. We propose the deactivation pathways in homogeneous solution are prevented by the immobilization: modified electrode reversibility is increased for a one-electron oxidation reaction. The modified electrodes were used to catalytically oxidize p-anisyl alcohol and 1-((benzyloxy)methyl)-4-methoxybenzene, selectively, to the corresponding benzaldehyde and benzyl ester, respectively

Condition monitoring of an advanced gas-cooled nuclear reactor core

A critical component of an advanced gas-cooled reactor station is the graphite core. As a station ages, the graphite bricks that comprise the core can distort and may eventually crack. Since the core cannot be replaced, the core integrity ultimately determines the station life. Monitoring these distortions is usually restricted to the routine outages, which occur every few years, as this is the only time that the reactor core can be accessed by external sensing equipment. This paper presents a monitoring module based on model-based techniques using measurements obtained during the refuelling process. A fault detection and isolation filter based on unknown input observer techniques is developed. The role of this filter is to estimate the friction force produced by the interaction between the wall of the fuel channel and the fuel assembly supporting brushes. This allows an estimate to be made of the shape of the graphite bricks that comprise the core and, therefore, to monitor any distortion on them

The preservation of quartz grain surface textures following vehicle fire and their use in forensic enquiry

During a terrorist trial, dispute arose as to whether the temperature produced in a car fire was sufficient to destroy quartz grain surface textures. A series of seven sequential experiments showed that the temperature for quartz surface texture modification/destruction and the production of vugs, vesicles and glassy precipitation ('snowdrifting') occurred at 1200 degrees C under normal atmospheric conditions. By adding a number of man-made and natural substances, it was found that only the presence of salts depressed this modification temperature (to 900 degrees C). Experiments to determine the temperature of fire in a car indicated that the maximum temperature produced under natural conditions (810 degrees C) was insufficient to affect the quartz grain Surface textures. These results confirm the use of surface texture analysis of quartz grains recovered from the remains of cars Subjected to fire and their use as a forensic indicator. (C) 2008 Forensic Science Society. Published by Elsevier Ireland Ltd. All rights reserved

Hot electrons in low-dimensional phonon systems

A simple bulk model of electron-phonon coupling in metals has been surprisingly successful in explaining experiments on metal films that actually involve surface- or other low-dimensional phonons. However, by an exact application of this standard model to a semi-infinite substrate with a free surface, making use of the actual vibrational modes of the substrate, we show that such agreement is fortuitous, and that the model actually predicts a low-temperature crossover from the familiar T^5 temperature dependence to a stronger T^6 log T scaling. Comparison with existing experiments suggests a widespread breakdown of the standard model of electron-phonon thermalization in metals

Quantum Force in Superconductor

Transitions between states with continuous (called as classical state) and discrete (called as quantum state) spectrum of permitted momentum values is considered. The persistent current can exist along the ring circumference in the quantum state in contrast to the classical state. Therefore the average momentum can changes at the considered transitions. In order to describe the reiterated switching into and out the quantum state an additional term is introduced in the classical Boltzmann transport equation. The force inducing the momentum change at the appearance of the persistent current is called as quantum force. It is shown that dc potential difference is induced on ring segments by the reiterated switching if the dissipation force is not homogeneous along the ring circumference. The closing of the superconducting state in the ring is considered as real example of the transition from classical to quantum stateComment: 4 pages, RevTex, 0 figure

Bars and Cold Dark Matter Halos

The central part of a dark matter halo reacts to the presence and evolution of a bar. Not only does the halo absorb angular momentum from the disk, it can also be compressed and have its shape modified. We study these issues in a series of cosmologically motivated, highly resolved N-body simulations of barred galaxies run under different initial conditions. In all models we find that the inner halo's central density increases. We model this density increase using the standard adiabatic approximation and the modified formula by Gnedin et al. and find that halo mass profiles are better reproduced by this latter. In models with a strong bar, the dark matter in the central region forms a bar-like structure (``dark matter bar''), which rotates together with the normal bar formed by the stellar component (``stellar bar''). The minor-to-major axial ratio of a halo bar changes with radius with a typical value 0.7 in the central disk region. DM bar amplitude is mostly a function of the stellar bar strength. Models in which the bar amplitude increases or stays roughly constant with time, initially large (40%-60%) misalignment between the halo and disk bars quickly decreases with time as the bar grows. The halo bar is nearly aligned with the stellar bar (~10 degrees lag for the halo) after ~2 Gyr. The torque, which the halo bar exerts on the stellar bar, can serve as a mechanism to regulate the angular momentum transfer from the disk to the halo.Comment: Modified version after referee's suggestions. 17 pages, 12 figures, accepted by Ap

Technical management techniques for identification and control of industrial safety and pollution hazards

Constructive recommendations are suggested for pollution problems from offshore energy resources industries on outer continental shelf. Technical management techniques for pollution identification and control offer possible applications to space engineering and management

Using stochastic acceleration to place experimental limits on the charge of antihydrogen

Assuming hydrogen is charge neutral, CPT invariance demands that antihydrogen also be charge neutral. Quantum anomaly cancellation also demands that antihydrogen be charge neutral. Standard techniques based on measurements of macroscopic quantities of atoms cannot be used to measure the charge of antihydrogen. In this paper, we describe how the application of randomly oscillating electric fields to a sample of trapped antihydrogen atoms, a form of stochastic acceleration, can be used to place experimental limits on this charge